Microwavea-Dipole Transitions of CH2DOH and CHD2OH in Excited Torsional States
✍ Scribed by C.Richard Quade; Mujian Liu; Indranath Mukhopadhyay; Chun Fu Su
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 181 KB
- Volume
- 192
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
✦ Synopsis
Previously identified, measured, and rotationally assigned but unpublished J ϭ 0 -1 and 1-2 microwave a-dipole lines for excited states of the torsion for CH 2 DOH and CHD 2 OH are given torsional assignments for the first four excited states. The troublesome assignments were for the K Ϫ1 ϭ 0 lines of the o 2 state of CH 2 DOH and the e 2 state of CHD 2 OH, where a resonance is found for the J 0J levels. The assignment for these states was facilitated by combination differences with the b-or c-dipole intratorsional state transitions, relative intensities, and FIR combination differences for the e 2 and e 3 states of CH 2 DOH. A few new b-and c-dipole assignments are reported for o 2 of CH 2 DOH and e 2 of CHD 2 OH. Transitions for these two states have been analyzed to estimate the strength of the resonant interaction and energy difference for the levels involved and to estimate how well the theory is predicting the K Ϫ1 -dependent torsional energy levels. The empirically determined ⌬ B and ⌬C from nonrigidity for each species for the four excited states should prove helpful for future calculations of vibration-internal rotation-overall rotation interactions in these molecules.
📜 SIMILAR VOLUMES
The zeroth-order kinetic energy is developed for the vibrating-rotating-internally rotating CH(2)DOH and CHD(2)OH molecules using the general theory of Guan and Quade for the vibration-rotation-large amplitude internal motion interactions in molecules. A T transformation is applied to obtain the nec
A global analysis of reported microwave (MW) millimeter wave (MMW), and Fourier-transform far-infrared (FTFIR) spectra of the CD3OH isotopic species of methanol has been carried out for the first two torsional states (nut = 0 below the barrier and nut = 1 straddling the barrier) of the ground vibrat
Rotational and centrifugal distortion constants as well as dipole moments in the three lowest-lying vibrational states of ketene, n 5 , n 6 , and n 9 , have been determined from millimeterwave measurements in the range 40 -165 GHz.