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Addition polymerization of norbornene, 5-vinyl-2-norbornene and 2-methoxycarbonyl-5-norbornene with a catalyst based on a palladium(0) precursor complex

✍ Scribed by Tatsuya Saito; Yasuo Wakatsuki


Book ID
113857511
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
526 KB
Volume
53
Category
Article
ISSN
0032-3861

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Oligomers and soluble polymers from the
✍ Frederik Blank; Harald Scherer; Christoph Janiak πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 438 KB

Oligomeric vinyl polynorbornene (2 to ∼12 monomer units) was obtained via hydrooligomerization of norbornene (NB) using the cationic palladium complexes [Pd(PPh 3 ) n (NCCH 3 ) 4-n ](BF 4 ) 2 [n = 0 (1), 3 (2)] at different hydrogen pressures. The vinyl polymerization of norbornene (NB) in the ionic