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Addition polymerization of 5-ethylidene-2-norbornene by cationic palladium cationic complex and subsequent derivatization

✍ Scribed by Luhai Wang; Xiaoya Wang; Min Yang; Yige Wang; Li Li; Binyuan Liu; Il Kim


Book ID
107691786
Publisher
The Polymer Society of Korea
Year
2011
Tongue
English
Weight
857 KB
Volume
19
Category
Article
ISSN
1598-5032

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Oligomers and soluble polymers from the
✍ Frederik Blank; Harald Scherer; Christoph Janiak πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 438 KB

Oligomeric vinyl polynorbornene (2 to ∼12 monomer units) was obtained via hydrooligomerization of norbornene (NB) using the cationic palladium complexes [Pd(PPh 3 ) n (NCCH 3 ) 4-n ](BF 4 ) 2 [n = 0 (1), 3 (2)] at different hydrogen pressures. The vinyl polymerization of norbornene (NB) in the ionic