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Polymerization of 5-vinyl-2-norbornene with TiCl3 and alkylaluminium catalysts

✍ Scribed by Kiyoshi Endo; Kazuyoshi Fujii; Takayuki Otsu

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
349 KB
Volume
197
Category
Article
ISSN
1022-1352

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The main kinetic laws governing 4-methylpentene-I (MP) polymerization and copolymerization with propylene (P) on the catalytic system TiCI 3 + (C2Hs)gAIC1 between 30 and 70 Β° were studied. The MP homopolymerization is kinetically first-order in monomer and TiCl> The effective activation energy is 8'

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## Abstract The polymerization of norbornene (NBE) was investigated in the presence of two novel pyrazolylimine nickel complexes [2‐(C~3~HN~2~Me~2~‐3,5){C(Ph)ο£Ύ[4‐R~2~C~6~H~2~(R~1~)~2~‐2,6]}NiBr~2~ (complex 1, R~1~ = ^i^Pr and R~2~ = H; complex 2, R~1~ = H and R~2~ = NO~2~)] activated by methylalumi