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Addition of sulfenyl chlorides to the cyanogen bond in activated nitriles

โœ Scribed by H. Kristinsson


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
75 KB
Volume
14
Category
Article
ISSN
0040-4039

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Addition of chlorine to the cyanogen bon
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Chlorine adds to activated cyano groups to give substituted N-chloroformimidoyl chlorides, as was reported by several authors. 2,3,4.

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cyanuric chloride. Conditions which accelerate the trimerization of the cyanogen chloride, such as presence of Lewis acids, HCl. HzO, and a ratio of Cl2 : CICN < 1:1, should therefore be avoided. Compound ( I ) , which is a colorless liquid having b.p. 87 "C, can be distilled under normal pressure.

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Die Reaktion von Benzylidenmalononitrilen mit Cyanthioacetamid (1) ergibt je nach den Reaktionsbedingungen entweder Thiopyrane oder Pyridine. Die Strukturen der Reaktionsprodukte wurden mittels l3C-NMR aufgeklart. In the last decade we have been involved in a program aiming at efficient syntheses o