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Addition of sulfur chlorides to the cyanogen bond in sulfonyl cyanides

โœ Scribed by M.S.A. Vrijland

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
101 KB
Volume
15
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Chlorine is known to add to the activated cyan0 group of sulfonyl cyanides, as was reported in our previous paper'.

๐Ÿ“œ SIMILAR VOLUMES

Addition of chlorine to the cyanogen bon
Addition of chlorine to the cyanogen bond in sulfonyl cyanides
โœ M.S.A. Vrijland; J.Th. Hackmann ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 71 KB

Chlorine adds to activated cyano groups to give substituted N-chloroformimidoyl chlorides, as was reported by several authors. 2,3,4.

Addition of Acyl Chlorides to the C N Bo
Addition of Acyl Chlorides to the C N Bond of Cyanates
โœ Dr. E. Grigat ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 123 KB ๐Ÿ‘ 1 views

cyanuric chloride. Conditions which accelerate the trimerization of the cyanogen chloride, such as presence of Lewis acids, HCl. HzO, and a ratio of Cl2 : CICN < 1:1, should therefore be avoided. Compound ( I ) , which is a colorless liquid having b.p. 87 "C, can be distilled under normal pressure.