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Addition of molecular fluorine to 7-oxabicyclo[2.2.1]hept-5-ene derivative and conversion to fluorine substituted deoxyhexofuranosides

✍ Scribed by Akemi Toyota; Minaho Uchiyama; Chikara Kaneko

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 550 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)00317-7

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✦ Synopsis

Addition of molecular fluorine m 7-oxabicyclo[2.2.1]hept-2-ene derivative (1) has been found to give exo,exo-difluoro adduct in fair yield. The adduct was converted to various 2,3-difluefo ribofuranosides and 2,3-ditlu~o dbofunmosyl acetate derivatives were transformed selectively to [~pyrimidine nueleoside analogs v/a unique glycosilatim process in the presence of TMSBr.

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