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ChemInform Abstract: Addition of Molecular Fluorine to 7-Oxabicyclo(2.2.1)hept-5-ene Derivative and Conversion to Fluorine Substituted Deoxyhexofuranosides.

✍ Scribed by A. TOYOTA; M. UCHIYAMA; C. KANEKO

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199738083

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✦ Synopsis

Addition of Molecular Fluorine to 7-Oxabicyclo(2.2.1)hept-5-ene Derivative and Conversion to Fluorine Substituted Deoxyhexofuranosides.

-Addition of F2 to the 7-oxabicycloheptene (I) yields the exo,exodifluoro adduct (II) in fair yield. (II) can be transformed into pyrimidine nucleoside analogues such as (XII). -(TOYOTA, A.; UCHIYAMA, M.;

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