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Addition of Grignard reagents and ketone enolates to the arene in (arene)manganese tricarbonyl cations

✍ Scribed by Chung, Young Keun; Williard, Paul G.; Sweigart, Dwight A.


Book ID
127300274
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
531 KB
Volume
1
Category
Article
ISSN
0276-7333

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## Abstract The magnesium 3,3‐dimethylcyclohex‐1‐enolate **1i**, formed in the copper catalyzed addition of methylmagnesium iodide to 3‐methylcyclohex‐2‐enone, has been subjected to regiospecific electrophilic reactions such as acylation, alkylation, and aldol condensation in order to find a new ac