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Adamantanone : A model to assess the position of the transition state in nucleophilic addition reactions to carbonyl compounds.

✍ Scribed by P. Geneste; G. Lamaty; C. Moreau; J-P. Roque

Publisher: Elsevier Science
Year: 1970
Tongue: French
Weight: 218 KB
Volume: 11
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89333-8

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✦ Synopsis

As we haVe previously pointed out], the position of the Transition State along the reaction coordinate is a matter of controversy among workers in the field of nucleophilic addition reactions to carbonyl compounds. Some authors claim that the transition state is always "Reactant-like" whatever may be the nucleophile ; others think, on the contrary, that the structure of the transition state depends upon the nucleophile and can be either "Reactant-like", or "Product-like" or somewhere in between.

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