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Acylsilanes and C-stannylimines as anion equivalents

โœ Scribed by Degl'Innocenti, Alessandro; Pike, Stephen; Walton, David R. M.; Seconi, Giancarlo; Ricci, Alfredo; Fiorenza, Mariella

Book ID
120213815
Publisher
The Royal Society of Chemistry
Year
1980
Tongue
English
Weight
176 KB
Volume
24
Category
Article
ISSN
0022-4936

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ChemInform Abstract: Behavior of Dioxola
ChemInform Abstract: Behavior of Dioxolanones as Chiral Acyl Anion Equivalents.
โœ R. A. AITKEN; A. W. THOMAS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB ๐Ÿ‘ 2 views

Behavior of Dioxolanones as Chiral Acyl Anion Equivalents. -Deprotonation of 1,3-dioxolan-4-ones [cf. (I)] and following alkylation gives products (III). Their flash vacuum pyrolysis yields ketones (IV) (with concomitant loss of CO and acetone) showing (I) to be acyl anion equivalents. Conjugate ad