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3-benzyloxy-1-isocyanopropenes. Synthesis and use as 3-hydroxypropanoyl anion equivalents

โœ Scribed by Kazuhiro Kobayashi; Hideki Akamatsu; Keiichiro Takada; Osamu Morikawa; Hisatoshi Konishi

Book ID
103410143
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
216 KB
Volume
37
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Sulfur heterocycles. I. Use of 4,4-dimet
Sulfur heterocycles. I. Use of 4,4-dimethyl-1,3-oxathiolane-3,3-dioxide as a carbonyl anion equivalent
โœ George W. Gokel; Harold M. Gerdes; David E. Miles; John M. Hufnal; Glenn A. Zerb ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

The title heterocycle is used as a carbonyl anion equivalent in the preparation of aldehydes and or-silyl ketones; the key step is the thermal demasking of the heterocycle by loss of isobutylene and sulfur dioxide.