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3-Nitrocycloalkenones, synthesis and use as reverse affinity cycloalkynone equivalents

โœ Scribed by E.J. Corey; Herbert Estreicher


Book ID
104243617
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
243 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœ Josรฉ M. Villalgordo; Heinz Heimgartner ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 586 KB

## The synthesis of a novel heterospirocyclic 3-amino-2H-asirine based on the reaction between amide enolates and diphenylphosphorochloridate is described. This compound has been shown to be a useful amino acid equivalent and the synthesis of a model m@pdde was achieved in good overall yields. 164