Acylation of butadieneiron tricarbonyl
โ Scribed by K. N. Anisimov; G. K. Magomedov; N. E. Kolobova; A. G. Trufanov
- Book ID
- 112423465
- Publisher
- Springer
- Year
- 1970
- Tongue
- English
- Weight
- 428 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1573-9171
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๐ SIMILAR VOLUMES
## Abstract A complete analysis of the proton coupled ^13^C spectrum of butadieneiron tricarbonyl is presented. The structure of the diene ligand is discussed on the basis of vicinal C,H and H,H coupling constants as well as ^2^__J__(HH), ^1^__J__(CH) and ^1^__J__(CC) data. These data are interpret
reacts with aci The anion derived by deprotonating (cycloheptatriene)Fe(CO)3 'd chlorides to give exo C-7 substitution. isomerized to C-5 on treatment with base. The acyl group is The readily deprotonated; the C-l acylated products can be resulting anions react at oxygen with acyl chlorides and Me3S