Stereocontrolled acylation of (η4-cycloheptatriene)iron tricarbonyl

✍ Scribed by Gregory M Williams; Duane E Rudisill

• Book ID: 104218903
• Publisher: Elsevier Science
• Year: 1986
• Tongue: French
• Weight: 235 KB
• Volume: 27
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)84823-6

✦ Synopsis

reacts with aci The anion derived by deprotonating (cycloheptatriene)Fe(CO)3 'd chlorides to give exo C-7 substitution. isomerized to C-5 on treatment with base. The acyl group is The readily deprotonated; the C-l acylated products can be resulting anions react at oxygen with acyl chlorides and Me3SiC1,