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Reaction of tricarbonyl(η6-cycloheptatriene)manganese cation with phosphorus ylides

✍ Scribed by Si-geun Lee; Young Keun Chung; Tae-Sung Yoon; Whanchul Shin

Book ID
103230402
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
513 KB
Volume
486
Category
Article
ISSN
0022-328X

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✍ Cornelius G. Kreiter; Norbert K. Wachter; Guido J. Reiß 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB

Mn(η 5 -C 6 H 7 )(CO) 3 ] (1) forms highly reactive [Mn(η 5 -adducts [Mn(η 3:2 -C 12 H 11 R 2 RЈ 2 )(CO) 3 ] (5A-5E), and the 1:3 adduct [Mn{η 3:2:2 -C 15 H 13 (CH 3 ) 6 }(CO) 2 ] (6A). The constitu-C 6 H 7 )(CO) 2 (THF)] (2) upon UV irradiation in THF at 208 K. Solvent complex 2 reacts between 208