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Reactions of (η-methylcyclopentadienyl) manganese tricarbonyl with primary amines

✍ Scribed by S.C. Srivastava; A.K. Shrimal; Amar Srivastava

Book ID: 103228956
Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 291 KB
Volume: 414
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(91)83242-v

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Mn(η 5 -C 6 H 7 )(CO) 3 ] (1) forms highly reactive [Mn(η 5 -adducts [Mn(η 3:2 -C 12 H 11 R 2 RЈ 2 )(CO) 3 ] (5A-5E), and the 1:3 adduct [Mn{η 3:2:2 -C 15 H 13 (CH 3 ) 6 }(CO) 2 ] (6A). The constitu-C 6 H 7 )(CO) 2 (THF)] (2) upon UV irradiation in THF at 208 K. Solvent complex 2 reacts between 208