Acyl rearrangement and the structures of some esters related to pyridoxine
β Scribed by W. Korytnyk; B. Paul
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 256 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Comparative studies of enantioselectivities and diastereoselectivities in the hydrolysis reactions of acylals and 50:50 threo-erythro mixtures of the esters of related secondary alcohols with Candida rugosa lipase gave significant information about the reactivity order in the enzymatic hydrolysis of
Experimental evidence shows that the DABCO catalysed rearrangement of allylic esterrproceedsvioatwo~mechanism,ratherthanasinglepsth,ashasbeenpreviously proposed. TheeffectivenesofothercatalystsaswellasE:ZratiosfortheseDABCOcatalysed reactions have also been detedmd.