Study of the acyl transfer reaction: Structure and properties of glycerol carbonate esters
✍ Scribed by Zéphirin Mouloungui; Sandrine Pelet
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 243 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1438-7697
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📜 SIMILAR VOLUMES
The acetylenic and cumulenic forms of carbyne (a and b-carbyne, respectively) have been obtained simultaneously by oxidative coupling of dicopper acetylide under Glaser conditions. Carbynes having copper atoms, or phenyl groups, at the ends of the chains were successfully synthesized. At room temper
Acyl-4-benzylpyridinium salts 4 containing nonnucleo-by the pyridine moiety of 4, which splits off and functions as a Lewis base to intercept the BF 3 acid. The structural and philic anions X -such as CF 3 SO 3 -, FSO 3 -, and BF 4 -can be generated quantitatively and in situ from 1-acyl-4-electroni
## Abstract An intermolecular Pd/PPh~3~‐catalyzed transesterification of diallyl carbonate with glycerol to generate glycerol carbonate has been developed. Analysis of the reaction kinetics in THF indicates a first‐order dependence on Pd and diallyl carbonate, that the Pd bears two phosphines durin