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Some mechanistic and synthetic aspects of the DABCO catalysed rearrangement of allylic esters.

✍ Scribed by Paul H. Mason; Neville D. Emslie

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
461 KB
Volume
50
Category
Article
ISSN
0040-4020

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✦ Synopsis

Experimental evidence shows that the DABCO catalysed rearrangement of allylic esterrproceedsvioatwo~mechanism,ratherthanasinglepsth,ashasbeenpreviously proposed. TheeffectivenesofothercatalystsaswellasE:ZratiosfortheseDABCOcatalysed reactions have also been detedmd.

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