The relation between activity and acidity in a variety of Y zeolite catalysts for the transformation of small olefins: ethene, propene, 1-butene and iso-butene, is presented. The acid site distribution of these samples was estimated by temperature-programmed desorption of ammonia, by using a numeric
Activity–acidity relationship in zeolite ZSM-5. Application of Brönsted-type equations
✍ Scribed by Carla Costa; I.P Dzikh; José Manuel Lopes; Francisco Lemos; Fernando Ramôa Ribeiro
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 197 KB
- Volume
- 154
- Category
- Article
- ISSN
- 1381-1169
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Broad-line 'H NMR and 'H MAS NMR were used to determine the geometry of the Bransted acidic sites in zeolites H-ZSM-5. The signals obtained correspond to bridging hydroxyl groups in Si-OH-Al arrangements with an H-Al distance of 0.246-0.252 nm. The concentration of hypothetical SiOHSi groups must be
Acidity of mesoporous HZSM-5 prepared using amphiphilic organosilane template molecules was measured. Brønsted acid sites were observed in the prepared sample, and the number and the strength of Brønsted acid sites were determined quantitatively by a method of infrared-mass spectroscopy/temperature-
A zinc-modi®ed ZSM-5 catalyst was prepared by a solid-state reaction between zinc dust and H-ZSM-5. The resulting catalyst is as active for the aromatization of ethane as zinc-modi®ed ZSM-5 prepared by impregnation.