Activation of cobalt-nitro complexes by Lewis acids: catalytic oxidation of alcohols by molecular oxygen
β Scribed by Tovrog, Benjamin S.; Diamond, Steven E.; Mares, Frank; Szalkiewicz, Andrew
- Book ID
- 125494767
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 716 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH 3 CN) 4 NO 2 ](A) 2 (A=PF 6 (1) or BF 4 (2)) has been studied in acetonitrile under P(O 2 )=20 atm, T=120 β’ C, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1
The oxidation of allylic and benzylic alcohols to aldehydes oxygen, in the presence of the bifunctional rutheniumcopper system (nPr 4 N)(RuO 4 )-CuCl acting as the catalyst. can be carried out at room temperature with molecular The oxidation of alcohols to aldehydes and ketones is a species [RuCl 2