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Acidity of hydrocarbons. XLVIII. Kinetic acidities of mono-, di-, and triarylmethanes toward lithium cyclohexylamide

✍ Scribed by Streitwieser, A.; Granger, M. R.; Mares, F.; Wolf, R. A.

Book ID: 120896528
Publisher: American Chemical Society
Year: 1973
Tongue: English
Weight: 640 KB
Volume: 95
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00794a023

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Acidity of hydrocarbons. XLVI. Equilibri

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Note that this equation results from our latest least squares analysis differs slightly from those given previously. (1965).

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We have shown recently (1) that the kinetic acidity of the bridgehead position of triptycene, I, can be quantitatively accounted for on the basis of the s-character in the C-H bond as measured by J13C\_H, and by the inductive field effect of the aryl carbons as measured by Cl/r. The success of the C

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Acidity of hydrocarbons. I. Equilibrium

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