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Acidity of hydrocarbons. XLVI. Equilibrium ion-pair acidities of mono-, di-, and triarylmethanes toward cesium cyclohexylamide

โœ Scribed by Streitwieser, A.; Murdoch, J. R.; Haefelinger, G.; Chang, C. J.

Book ID
120896527
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
864 KB
Volume
95
Category
Article
ISSN
0002-7863

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Acidity of Hydrocarbons. XLI. Kinetic ac
Acidity of Hydrocarbons. XLI. Kinetic acidities of bridgehead hydrogens in benzotriptycene and ethenoanthracene towards cesium cyclohexylamide
โœ A. Streitwieser Jr.; M.J. Maskornick; G.R. Ziegler ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

We have shown recently (1) that the kinetic acidity of the bridgehead position of triptycene, I, can be quantitatively accounted for on the basis of the s-character in the C-H bond as measured by J13C\_H, and by the inductive field effect of the aryl carbons as measured by Cl/r. The success of the C