Acidity of Hydrocarbons. XLI. Kinetic ac
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A. Streitwieser Jr.; M.J. Maskornick; G.R. Ziegler
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Article
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1971
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Elsevier Science
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French
โ 193 KB
We have shown recently (1) that the kinetic acidity of the bridgehead position of triptycene, I, can be quantitatively accounted for on the basis of the s-character in the C-H bond as measured by J13C\_H, and by the inductive field effect of the aryl carbons as measured by Cl/r. The success of the C