Acid catalyzed rearrangements of 4-methyl-4-cyanocyclohexadienone
โ Scribed by John N. Marx; Joe Zuerker; Young-sook Paik Hahn
- Book ID
- 103402577
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 148 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The acid-catalyzed rearrangements of three model tricyclo[4.3.2] propellane derivatives have been explored. In each case the observed products are proposed to arise via a concerted 1,2-shift of the cyclobutane bond having an antiperiplanar alignment with the leaving group (i.e., stereoelectronic con
Received in USA 25 Jamaxy 1975; xeoelved in UK for publioatlon 17 Maroh 1975) Reaction of naphthalenone Lwith protic acids (such as sulfuric acid In acetic acid or water) gives approximately equal yields of the [3,41 rearrangesent product 2 and the [1,5] rearrangement product &2 These products can