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Acid catalyzed rearrangements of 4-methyl-4-cyanocyclohexadienone

โœ Scribed by John N. Marx; Joe Zuerker; Young-sook Paik Hahn


Book ID
103402577
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
148 KB
Volume
32
Category
Article
ISSN
0040-4039

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Acid-catalyzed rearrangements of tricycl
โœ Amos B. Smith III; Barry A. Wexler ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 260 KB

The acid-catalyzed rearrangements of three model tricyclo[4.3.2] propellane derivatives have been explored. In each case the observed products are proposed to arise via a concerted 1,2-shift of the cyclobutane bond having an antiperiplanar alignment with the leaving group (i.e., stereoelectronic con

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โœ Bernard Miller; Mohammed Reza Saidi ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

Received in USA 25 Jamaxy 1975; xeoelved in UK for publioatlon 17 Maroh 1975) Reaction of naphthalenone Lwith protic acids (such as sulfuric acid In acetic acid or water) gives approximately equal yields of the [3,41 rearrangesent product 2 and the [1,5] rearrangement product &2 These products can