✦ LIBER ✦

Acid-catalyzed rearrangements of tricyclo[4.3.2]Propellane derivatives

✍ Scribed by Amos B. Smith III; Barry A. Wexler

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 260 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80244-6

No coin nor oath required. For personal study only.

✦ Synopsis

The acid-catalyzed rearrangements of three model tricyclo[4.3.2] propellane derivatives have been explored. In each case the observed products are proposed to arise via a concerted 1,2-shift of the cyclobutane bond having an antiperiplanar alignment with the leaving group (i.e., stereoelectronic control).

📜 SIMILAR VOLUMES

Acid-catalyzed rearrangements of 7-oxyge

Acid-catalyzed rearrangements of 7-oxygenated norbornenyl derivatives

✍ Vera K. Jones; Lee B. Jones 📂 Article 📅 1970 🏛 Elsevier Science 🌐 French ⚖ 152 KB

Synthesis and Facile Rearrangement of 10

Synthesis and Facile Rearrangement of 10,10-Dicarbonyl-substituted [4.3.1]Propellane Derivatives.

✍ Yoshito Tobe; Takuji Kusumoto; Shiho Minakata; Rui Umeda; Motohiro Sonoda; Koich 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 122 KB

Rhodium catalyzed isomerization of tricy

Rhodium catalyzed isomerization of tricyclo [3.2.2.02,4] nonadiene

✍ T.J. Katz; S.A. Cerefice 📂 Article 📅 1969 🏛 Elsevier Science 🌐 French ⚖ 32 KB

Rhodium catalyzed isomerization of tricy

Rhodium catalyzed isomerization of tricyclo[3.2.2.02,4]Nonatriene

✍ Thomas J. Katz; Steven A. Cerefice 📂 Article 📅 1969 🏛 Elsevier Science 🌐 French ⚖ 156 KB

In 1966 it was first reported that rhodium catalyzes a cycloaddition reaction (norbornadiene + 5% Rh/C) (1). Subsequently similar reactions were found to occur not only with some other hydrocarbons and rhodium on carbon (2), but also with coordination complexes of rhodium

Rearrangement of the trans-Tricyclo[4.2.

Rearrangement of the trans-Tricyclo[4.2.0.01,3]oct-4-enyl Skeleton

✍ Elena S. Koltun; Steven R. Kass 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 145 KB

AbstractÐThe acetolysis of a tosylate with a novel tricyclic skeleton was examined. Two major products (a tosylate and an acetate) are formed and both are the result of a skeletal rearrangement. A mechanism to account for the observed products is proposed and preliminary kinetic data are reported.

ChemInform Abstract: Acid-Catalyzed Rear

ChemInform Abstract: Acid-Catalyzed Rearrangements of Allyl 4-Hydroxybenzoate and 3-Methylbut-2-enyl-4-hydroxybenzoate.

✍ Sankar P. Dey; Dilip K. Dey 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 25 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v