Regioselective generation of the C(2)-carbocation a of tricyc10[4.2.2.0',~]decane (1) by treatment of both corresponding epimeric alcohols 5 and 6 with BF, and trapping the rearranged tricy~lo[S.3.0.O~~~]decan-7-yl carhocation b with Et,SiH as hydride-ion donor (ionic hydrogenation) gives the corres
โฆ LIBER โฆ
Acid-catalyzed rearrangement of tricyclo[4.4.0.2,7]decan-3-ols
โ Scribed by Ratcliffe, Bruce E.; Heathcock, Clayton H.
- Book ID
- 125930560
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 908 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0022-3263
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