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Acid-catalyzed oxidation of carboxymethyl cellulose. Kinetics and mechanism of permanganate oxidation of carboxymethyl cellulose in acid perchlorate solutions

โœ Scribed by Refat M. Hassan; Doaa A. Abdel-Kader; Saddek M. Ahmed; Ahmed Fawzy; Ishaq A. Zaafarany; Basim H. Asghar; Hideo D. Takagi

Book ID
118427184
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
487 KB
Volume
11
Category
Article
ISSN
1566-7367

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โœ Ali M. Shaker ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 115 KB

The kinetics and mechanism of the disproportionation of MnO - 4 via [CMC-MnVIO 2- 4 ] intermediate complex formation during the oxidation of carboxymethyl-cellulose (CMC) polysaccharide have been investigated spectrophotometrically at pH โ‰ฅ 12 and various temperatures (15-35 โ€ข C). The rate law was su