Acid-Catalyzed Ether Rearrangement: Total Synthesis of Isomimosifoliol and (±)-Dihydromimosifoliol
✍ Scribed by Arava, Veera Reddy; Malreddy, Sashibhushan; Thummala, Sreenivasulu Reddy
- Book ID
- 120037205
- Publisher
- Taylor and Francis Group
- Year
- 2012
- Tongue
- English
- Weight
- 398 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0039-7911
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📜 SIMILAR VOLUMES
Allyl vinyl ethers containing an acceptor function in the 2-position are useful substrates for the Lewis acid-catalyzed Claisen rearrangement. The first synthesis of acyclic 2-(1,3-oxazolin-2-yl)-substituted allyl vinyl ethers is reported. The Lewis acid catalyzed Claisen rearrangement of these ally
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## Abstract Aklanonic acid (1) and the derivatives 2 and 15a–f were prepared by Baker‐Venkataraman rearrangement of the corresponding __ortho__‐acetyl anthraquinone esters 13a–e and 14 using lithium hydride in THF.