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Acid-Catalyzed Stereoselective Rearrangement and Dimerization of Flavenes: Synthesis of Dependensin.

✍ Scribed by Mandar Deodhar; David StC Black; Naresh Kumar

Book ID
102008717
Publisher
John Wiley and Sons
Year
2007
Weight
19 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Acid-catalyzed rearrangement of pyran de
Acid-catalyzed rearrangement of pyran derivatives. An approach to the stereoselective synthesis of 1,3-diol derivatives
✍ Philip DeShong; David M Simpson; Ming-Teh Lin πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 274 KB

Peracid oxidation and HF-catalyzed treatment of furfuryl alcohol derivatives affords lactone products arising from a highly stereoselective rearrangement process. The lactones serve as precursors of highly functionahzed anti-1,3-dial derivatives. During the studies directed toward the total synthes