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Total synthesis of Aklanonic Acid and Derivatives by Baker-Venkataraman Rearrangement

✍ Scribed by Krohn, Karsten ;Roemer, Ernst ;Top, Michael

Book ID
102904258
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
949 KB
Volume
1996
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

Aklanonic acid (1) and the derivatives 2 and 15a–f were prepared by Baker‐Venkataraman rearrangement of the corresponding ortho‐acetyl anthraquinone esters 13a–e and 14 using lithium hydride in THF.

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4,6-Dimethoxy-3,7-dimethylcoumarin from
4,6-Dimethoxy-3,7-dimethylcoumarin from Colchicum decaisnei. Total synthesis by carbamoyl Baker-venkataraman rearrangement and structural revision to isoeugenetin methyl ether
✍ Alexey V. Kalinin; Victor Snieckus 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 287 KB

Coumarin (l) , the putative natural product isolated from Coichicurn decaisnei, has been shown, by spectroscopic analysis and total synthesis. to be isoeugenetin methyl ether (2a), a synthetic derivative of the isoeugenetin (2b), isolated from Eugeniu curvop~~~dlafa.