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Acid-catalyzed deuterium exchange of the indole ring protons in tryptamine derivatives

✍ Scribed by Kang, Sungzong; Witherup, Thomas H.; Gross, Steven

Book ID
126954012
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
419 KB
Volume
42
Category
Article
ISSN
0022-3263

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In acid-catalyzed reactions with 3-unsubstituted indoles 1,2-alkoxy-1,3-dioxolanes 2a-c behave as acyl equivalents. Depending on the substitution patterns of the reaction partners, the 1,3-dioxolanium ions 3a-c, generated in situ from the cyclic ortho esters by the action of sulfosalicylic acid, rea