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Carbonyl Reactions. XI. Deuterium Exchange in the Acid-catalyzed Isomerization of cis-Benzalacetophenone 1

✍ Scribed by Noyce, Donald S.; Woo, Gar Lok; Jorgenson, Margaret Jefraim


Book ID
126891318
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
518 KB
Volume
83
Category
Article
ISSN
0002-7863

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Synthesis of Chiral 1,3-Diamines Derived
✍ Dr. Koichi Kodama; Kazuyuki Sugawara; Prof. Takuji Hirose πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 438 KB πŸ‘ 1 views

## Abstract In this study, 13 different chiral 1,3‐diamines were synthesized from (βˆ’)‐__cis__‐2‐benzamidocyclohexanecarboxylic acid. They were successfully applied as ligands in the Cu‐catalyzed asymmetric Henry reaction between benzaldehyde and nitromethane. It was confirmed that the enantioselect