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Acid-catalyzed decomposition of hydroperoxides in the presence of ketones

✍ Scribed by L. V. Petrov; T. I. Drozdova; L. Ya. Lyuta; V. M. Solyanikov

Book ID
112448597
Publisher
Springer
Year
1990
Tongue
English
Weight
519 KB
Volume
39
Category
Article
ISSN
1573-9171

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The decomposition of organic hydroperoxi
The decomposition of organic hydroperoxides: Part III. Kinetics of the acid-catalyzed decomposition of benzyl-type hydroperoxides
✍ A. W. de Ruyter van Steveninck; E. C. Kooyman πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 799 KB

## Abstract The HClO~4~‐catalyzed decomposition of a number of alkylbenzyl hydroperoxides has been investigated by a study of the reaction kinetics in 50% w ethanol at 50Β°C. A Hammett relation (__p__ = ‐4.57) has been found to exist for the decomposition of ring‐substituted Ξ±,α‐dimethylbenzyl hydro