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Kinetics of decomposition of isopropylbenzene hydroperoxide catalyzed by dodecamolybdophosphoric acid

✍ Scribed by Kozhevnikov, I. V. ;Mastikhin, V. M. ;Matveev, K. I. ;Kirichenko, G. N. ;Churkin, Yu. V. ;Glazunova, V. I.

Book ID
112682799
Publisher
Springer
Year
1977
Tongue
English
Weight
214 KB
Volume
7
Category
Article
ISSN
0133-1736

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The decomposition of organic hydroperoxi
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✍ A. W. de Ruyter van Steveninck; E. C. Kooyman πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 799 KB

## Abstract The HClO~4~‐catalyzed decomposition of a number of alkylbenzyl hydroperoxides has been investigated by a study of the reaction kinetics in 50% w ethanol at 50Β°C. A Hammett relation (__p__ = ‐4.57) has been found to exist for the decomposition of ring‐substituted Ξ±,α‐dimethylbenzyl hydro