## Abstract The HClO~4~‐catalyzed decomposition of a number of alkylbenzyl hydroperoxides has been investigated by a study of the reaction kinetics in 50% w ethanol at 50°C. A Hammett relation (__p__ = ‐4.57) has been found to exist for the decomposition of ring‐substituted α,α‐dimethylbenzyl hydro
The acid-catalyzed decomposition of aliphatic hydroperoxides: reactions in the presence of alcohols
✍ Scribed by John O. Turner
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 190 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
## Abstract The cobalt‐catalyzed decomposition of __tert.__‐butyl hydroperoxide in the presence of a number of five‐membered heterocycles is described. With tetrahydrofuran displacement of the alpha‐hydrogen atom by a peroxy group is observed; with furan and pyrrole 1.4 addition of peroxy radicals
The titanium-catalyzed, asymmetric epoxidation of dialkyl-and phenylsubstituted allylic alcohols with various enantiomerically pure hydroperoxides has been examined in the presence of achiral diol ligands. Enantioselectivities with ee values up to 50% were achieved in the oxygen transfer from (-)-(S