Accurate Heats of Formation for BF n , BF n + , BCl n , and BCl n + for n = 1−3
✍ Scribed by Bauschlicher, Charles W.; Ricca, Alessandra
- Book ID
- 126891408
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 49 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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## Abstract Some __N__‐BH~3~, __N__‐BF~3~, __N__^+^‐CH~3~ and __N__^+^‐H imidazole derivatives have been prepared and their ^13^C, ^11^B and ^1^H NMR spectra studied. The effect of the different substituents was analysed. The isolobal character of the __N__‐BH~3~ and __N__‐CH~3~ derivatives is refl
Hydrostannation of N-heteroatom-substituted imines such as oxime ethers, hydrazones, oximes, nitrones, and N-sulfonyl imines using a combination of Bu 3 SnH and BF 3 •OEt 2 has been systematically studied. Not only aromatic aldimines but also kitimines and aliphatic imines were reduced to give the c