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Accurate Heats of Formation for SF n , SF n + , and SF n - for n = 1−6

✍ Scribed by Bauschlicher, Charles W.; Ricca, Alessandra

Book ID
118124924
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
47 KB
Volume
102
Category
Article
ISSN
1089-5639

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The small binding energies of the negati
The small binding energies of the negative cluster ions: SF5−(SF6)1, SF6−(SF6)1 and F−(SF6)n (n = 1 and 2), in the gas phase
✍ Kenzo Hiraoka; Akitaka Shimizu; Akihito Minamitsu; Masayuki Nasu; Susumu Fujimak 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 288 KB

The gas-phase clustering reactions of SF~, SF 6 and F-ions with SF 6 were measured using a high-pressure mass spectrometer. The bond energies of SFs--(SF6) 1 and SF6(SF6) 1 were estimated to be ~< 2.3 kcal/mol. The bond energies of F-(SF6) , with n = 1 and 2 were determined to be 5.4 and = 4.1 kcal/