Weak ion-molecule complexes of F−(CF4)n
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Kenzo Hiraoka; Masayuki Nasu; Susumu Fujimaki; Edgar W. Ignacio; Shinichi Yamabe
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Article
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1995
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Elsevier Science
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English
⚖ 329 KB
Gas-phase thermochemical stabilities and structures of cluster ions F-(CF4) n and CF~-(CF4) ~ have been studied with a high-pressure mass spectrometer and ab initio calculations. The F-... CF a bonding energy is found to be only 6.4 kcal/mol. Its geometry is of an ion-dipole complex along an Sr~2 re