Absolute Rate Expressions for Hydrogen Atom Abstraction from Molybdenum Hydrides by Carbon-Centered Radicals
β Scribed by Franz, James A.; Linehan, John C.; Birnbaum, Jerome C.; Hicks, Kenneth W.; Alnajjar, M. S.
- Book ID
- 126320449
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 164 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Absolute rate constants have been measured for the reactions of trichloromethylperoxyl radicals with cyclohexane, cyclohexene, and hexamethylbenzene. The CClsO, radicals were produced by pulse radiolysis of air-saturated CCl, solutions containing various amounts of the hydrocarbons. The rate constan
## Abstract Measurements of rates of oxygen absorption and steadyβstate peroxy radical concentrations for the autoxidation of tetralin in the presence of __tert__βbutyl hydroperoxide have shown that the rate constant for reaction of the __tert__βbutylperoxy radical with tetralin at 60Β°C is approxim