## Abstract Measurements of rates of oxygen absorption and steadyβstate peroxy radical concentrations for the autoxidation of tetralin in the presence of __tert__βbutyl hydroperoxide have shown that the rate constant for reaction of the __tert__βbutylperoxy radical with tetralin at 60Β°C is approxim
Absolute rate constants for hydrocarbon autoxidation. 25. Rate constants for hydrogen atom abstraction from alkanes by the tert -butylperoxy radical
β Scribed by Chenier, J. H. B.; Tong, S. B.; Howard, J. A.
- Book ID
- 120422328
- Publisher
- NRC Research Press
- Year
- 1978
- Tongue
- French
- Weight
- 326 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0008-4042
- DOI
- 10.1139/v78-498
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Absolute rate constants have been measured for the reactions of trichloromethylperoxyl radicals with cyclohexane, cyclohexene, and hexamethylbenzene. The CClsO, radicals were produced by pulse radiolysis of air-saturated CCl, solutions containing various amounts of the hydrocarbons. The rate constan
An important step in the initial oxidation of hydrocarbons at low to intermediate temperatures is the abstraction of H by hydroperoxyl radical (HO(2)). In this study, we calculate energy profiles for the sequence: reactant + HO(2) β [complex of reactants] β transition state β [complex of products] β