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Comparison of Hydrogen Atom Abstraction Rates of Terminal and Bridging Hydrides in Triosmium Clusters: Absolute Abstraction Rate Constants for Benzyl Radical

✍ Scribed by Franz, James A.; Kolwaite, Douglas S.; Linehan, John C.; Rosenberg, Edward


Book ID
127158496
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
78 KB
Volume
23
Category
Article
ISSN
0276-7333

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## Abstract Measurements of rates of oxygen absorption and steady‐state peroxy radical concentrations for the autoxidation of tetralin in the presence of __tert__‐butyl hydroperoxide have shown that the rate constant for reaction of the __tert__‐butylperoxy radical with tetralin at 60Β°C is approxim