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Absolute rate constants for the reactions of tert-butoxyl, tert-butylperoxyl, and benzophenone triplet with amines: the importance of a stereoelectronic effect

✍ Scribed by Griller, D.; Howard, J. A.; Marriott, P. R.; Scaiano, J. C.

Book ID
121295841
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
675 KB
Volume
103
Category
Article
ISSN
0002-7863

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Nucleophilic character of the tert-butyl
Nucleophilic character of the tert-butyl radical. Absolute rate constants for the reactions with substituted toluenes
✍ H. R. Dütsch; H. Fischer 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The decay of photochemically generated __tert__‐butyl radicals is studied at 48°C in 11 __m__‐ and __p__‐substituted toluenes by time‐resolved electron spin resonance spectroscopy. It is governed by the second‐order self‐termination perturbed by a pseudo‐first‐order reaction of the radi