Absolute rate constants for the reaction of tert-butylperoxy radicals with some m- and p-substituted toluenes
✍ Scribed by Howard, J. A.; Chenier, J. H. B.
- Book ID
- 126472784
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 277 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The decay of photochemically generated __tert__‐butyl radicals is studied at 48°C in 11 __m__‐ and __p__‐substituted toluenes by time‐resolved electron spin resonance spectroscopy. It is governed by the second‐order self‐termination perturbed by a pseudo‐first‐order reaction of the radi
## Abstract The decay of photochemically generated __tert__‐butyl radicals in methylcyclopentane solutions containing chloroform is studied by time‐resolved ESR spectroscopy. In the pure solvent it perfectly follows the second‐order rate law for radical self‐termination. Increasing chloroform conce