𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Absolute rate constants for the reaction of tert-butylperoxy radicals with some m- and p-substituted toluenes

✍ Scribed by Howard, J. A.; Chenier, J. H. B.


Book ID
126472784
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
277 KB
Volume
95
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Nucleophilic character of the tert-butyl
✍ H. R. Dütsch; H. Fischer 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The decay of photochemically generated __tert__‐butyl radicals is studied at 48°C in 11 __m__‐ and __p__‐substituted toluenes by time‐resolved electron spin resonance spectroscopy. It is governed by the second‐order self‐termination perturbed by a pseudo‐first‐order reaction of the radi

Rate constants for the reaction of tert-
✍ H.-R. Dütsch; H. Fischer 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 699 KB

## Abstract The decay of photochemically generated __tert__‐butyl radicals in methylcyclopentane solutions containing chloroform is studied by time‐resolved ESR spectroscopy. In the pure solvent it perfectly follows the second‐order rate law for radical self‐termination. Increasing chloroform conce