𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Absolute rate constants for the reaction of tert-butylperoxy radicals with trivalent phosphorus compounds

✍ Scribed by Furimsky, E.; Howard, J. A.

Book ID
126202299
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
612 KB
Volume
95
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Nucleophilic character of the tert-butyl
Nucleophilic character of the tert-butyl radical. Absolute rate constants for the reactions with substituted toluenes
✍ H. R. Dütsch; H. Fischer 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The decay of photochemically generated __tert__‐butyl radicals is studied at 48°C in 11 __m__‐ and __p__‐substituted toluenes by time‐resolved electron spin resonance spectroscopy. It is governed by the second‐order self‐termination perturbed by a pseudo‐first‐order reaction of the radi

On the accuracy of the hydroperoxide met
On the accuracy of the hydroperoxide method of determining absolute rate constants for hydrogen atom abstraction by the tert-butylperoxy radical
✍ J. A. Howard; J. H. B. Chenier 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB 👁 1 views

## Abstract Measurements of rates of oxygen absorption and steady‐state peroxy radical concentrations for the autoxidation of tetralin in the presence of __tert__‐butyl hydroperoxide have shown that the rate constant for reaction of the __tert__‐butylperoxy radical with tetralin at 60°C is approxim