Absolute rate constants for the reaction of O(3P) atoms with n-butane (kz) and NO(M = Ar) (k3) have been determined over the temperature range 298-439 K using a flash photolysis-NO2 chemiluminescence technique. The Arrhenius esprcssions obtained were k2 = 2.5 X 10 -11exp[-(4170 f 300)/RT] cm3 molecu
Absolute Rate Constants for the reaction of O(3P) with NO in Ar from 237 to 397 K
โ Scribed by Larry G. Anderson; Robert D. Stephens
- Book ID
- 103494999
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 192 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0047-2670
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๐ SIMILAR VOLUMES
Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO1 and FNO absorption transients, rate constants for reaction between CF90 and CFsO2 radicals with NO were determined, CFp02+NO+CF,O+N02 (3 ), CF,OtNO~CF,OtFNO(5).k~wasderivedtobe(1.68~0.26)X10~~'cm3molecuIe
## Abstract Earlier work on the reactions of O(^3^P) atoms with HCl and HBr has been extended by measuring rate constants for equation image A flowโtube method was used with chemiluminescent monitoring of the removal of atomic oxygen. Rate constants were measured at temperatures between 340 and 4