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Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals1

✍ Scribed by Avila, David V.; Ingold, K. U.; Lusztyk, J.; Dolbier,, W. R.; Pan, H.-Q.

Book ID
115485354
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
429 KB
Volume
61
Category
Article
ISSN
0022-3263

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## Abstract Absolute rate constants are reported for the addition of the 1‐[(__tert__‐butoxy)carbonyl]ethyl (= 2‐(1,1‐dimethylethoxy)‐1‐methyl‐2‐oxoethyl) radical ^.^CHMeCO~2~(__t‐__Bu) to several cyclic and monosubstituted alkenes in MeCN as obtained by time‐resolved electron paramagnetic resonanc