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Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution: New Evidence for Polar Interactions

โœ Scribed by Zytowski, Torsten; Fischer, Hanns


Book ID
111869795
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
153 KB
Volume
118
Category
Article
ISSN
0002-7863

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Absolute rate constants for the addition
โœ J. Q. Wu; H. Fischer ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 753 KB

Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants

Absolute Rate Constants for the Addition
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Absolute rate constants and thzir temperature dependence were determined by time-resolved electron spin resonance for the addition of the radicals PhcH, and PhcMe, to a variety of alkenes in toluene solution. To vinyl monomers CH,=CXY, PhCH, adds at the unsubstituted C-atom with rate constants rangi

Absolute Rate Constants for the Addition
โœ Hanns Fischer; Bernhard Knรผhl; Sylvainโ€…R.โ€…A. Marque ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 46 KB ๐Ÿ‘ 1 views

## Abstract Absolute rate constants are reported for the addition of the 1โ€[(__tert__โ€butoxy)carbonyl]ethyl (=โ€‰2โ€(1,1โ€dimethylethoxy)โ€1โ€methylโ€2โ€oxoethyl) radical ^.^CHMeCO~2~(__tโ€__Bu) to several cyclic and monosubstituted alkenes in MeCN as obtained by timeโ€resolved electron paramagnetic resonanc