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Absolute Rate Coefficient of the HCCO + NO Reaction over the Range T = 297−802 K

✍ Scribed by Carl, S. A.; Sun, Q.; Vereecken, L.; Peeters, J.

Book ID
126818075
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
136 KB
Volume
106
Category
Article
ISSN
1089-5639

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Absolute rate constants for the reaction of O(3P) atoms with n-butane (kz) and NO(M = Ar) (k3) have been determined over the temperature range 298-439 K using a flash photolysis-NO2 chemiluminescence technique. The Arrhenius esprcssions obtained were k2 = 2.5 X 10 -11exp[-(4170 f 300)/RT] cm3 molecu